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Kinetic studies of xylan hydrolysis of corn stover in a dilute acid cycle spray flow-through reactor

Hongman ZHANG, Qiang JIN, Rui XU, Lishi YAN, Zengxiang LIN

《化学科学与工程前沿（英文）》 2011年 第5卷 第2期   页码 252-257 doi: 10.1007/s11705-010-1010-y

摘要： Xylan of corn stover was pretreated with 1%, 2% and 3% (w/w) sulfuric acid at relatively low temperatures (90°C, 95°C and 100°C) in a dilute acid cycle spray flow-through reactor (DCF). The hydrolysis of xylan to its monomeric xylose was modeled by a series of first-order reactions. Both biphasic and Saeman hydrolysis models were applied to fit the experimental data. The results confirmed that the kinetic data of xylan hydrolysis fitted a first-order irreversible reaction model and the experimental data. The reaction rates of xylose monomer formation and degradation were sensitive to catalyst concentration and temperature. Higher catalyst concentration and lower reaction temperature result in high xylose yield. The activation energy for xylose formation and degradation were determined to be 112.9 and 101.0 kJ·mol , respectively. Over 90% theoretical xylose obtained from corn stover can be used to produce ethanol, xylitol and fumaric acid by fermentation.

关键词： corn stover     xylan hydrolysis     biphasic model     Saeman model     cycle spray     kinetics    

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燃油喷雾形态主动控制的可能性 Review

Masataka Arai

《工程（英文）》 2019年 第5卷 第3期   页码 519-534 doi: 10.1016/j.eng.2019.04.010

摘要：

内燃机（ICE）对于汽车是有吸引力的动力源，具有良好的可储存性、可运输性，同时需要供应高能量密度的液体燃料。具有高性能和低环境危害的紧凑型内燃机是内燃机发展趋势。未来必须把燃油喷雾智能主动控制的燃烧作为解决传统内燃机相关重大问题（如排放）的突破性技术。已发展出在喷雾期间形成预期的燃料喷射速率和喷射模式的技术，并且传统内燃机可以在一定程度上控制燃烧。但是在燃烧范围内，燃料在空间上的扩散并未取得预期进展。因此，对于燃烧的智能控制，新且有效的燃油喷雾主动控制技术是非常必要的。空化、闪蒸、喷雾- 喷雾相互作用、喷雾-壁面相互作用和空气流动是有可能实现燃油喷雾形态主动控制的基础。本文使用文献中的论据来讨论未来喷雾燃烧的智能紧凑内燃机中喷雾形态主动控制技术的可能性。

关键词： 内燃机，燃料喷雾，喷雾控制，喷雾形态，喷油器    

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Numerical investigation of the effects of fuel spray type on the interaction of fuel spray and hot porous

ZHAO Zhiguo, XIE Maozhao

《能源前沿（英文）》 2008年 第2卷 第1期   页码 59-65 doi: 10.1007/s11708-008-0022-5

摘要： The interaction between two types of fuel spray and a hot porous medium is studied numerically by using an improved version of KIVA-3V code. The improved KIVA-3V code is incorporated with an impingement model, a heat transfer model and a linearized instability sheet atomization (LISA) model to model the hollow cone spray. An evaporating fuel spray impingement on a hot plane surface was simulated under conditions of experiments performed by Senda to validate the reasonability of the KIVA-3V code. The numerical results conform well with experimental data for spray radius in the liquid and the vapor phases. Computational results on the interaction of two types of the fuel spray and the hot porous medium show that the fuel spray can be split, which provides conditions for quick evaporation of fuel droplets and mixing of fuel vapor with air. The possibility of fuel droplets from hollow cone spray crossing the porous medium reduces compared with that from solid cone spray, with the same initial kinetic energy of fuel droplets in both injection types.

关键词： improved version     impingement     atomization     hollow     radius    

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Particle formation of hydroxyapatite precursor containing two components in a spray pyrolysis process

W. Widiyastuti, Adhi Setiawan, Sugeng Winardi, Tantular Nurtono, Heru Setyawan

《化学科学与工程前沿（英文）》 2014年 第8卷 第1期   页码 104-113 doi: 10.1007/s11705-014-1406-1

摘要： The particle formation mechanism of hydroxyapatite precursor containing two components, Ca(OOCCH ) and (NH ) HPO with a ratio of Ca/P= 1.67, in a spray pyrolysis process has been studied by computational fluid dynamics (CFD) simulation on the transfer of heat and mass from droplets to the surrounding media. The focus included the evaporation of the solvent in the droplets, a second evaporation due to crust formation, the decomposition reaction of each component of the precursor, and a solid-state reaction that included the kinetic parameters of the precursor regarding its two components that formed the hydroxyapatite product. The rate of evaporation and the reacted fraction of the precursor both increased with temperature. The predicted average size of the hydroxyapatite particles agreed well with the experimental results. Therefore, the selected models were also suitable for predicting the average size of particles that contain two components in the precursor solution.

关键词： droplet     hydroxyapatite particle     CFD     tubular furnace     spray pyrolysis    

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Plasma spray coating on interconnector toward promoted solid oxide fuel cells and solid oxide electrolysis

《能源前沿（英文）》 doi: 10.1007/s11708-023-0901-9

摘要： Interconnector is a critical component to construct solid oxide cells (SOCs) stack. Oxidation of metallic interconnectors and Cr poisoning caused by oxidation are important factors that lead to long-term performance degradation of SOCs. Coating on the interconnector surface is an important approach to inhibit the oxidation and Cr migration of the interconnector. Herein, (La0.75Sr0.25)0.95MnO3–δ (LSM) and Mn1.5Co1.5O4 (MCO) are used to fabricate the coatings of interconnector. Two advanced thermal spray technology, atmospheric plasma spraying (APS) and low-pressure plasma spray (LPPS), are adopted for the coating preparation. The electrochemical performance, rising and cooling cycle stability, and Cr diffusion inhibition performance of the coatings are tested and evaluated. The result indicates that MCO can generate more uniform and denser coatings than LSM. In addition, MCO coatings prepared by LPPS shows the best electrochemical performance, rising and cooling cycle stability, and Cr diffusion inhibition. The initial area specific resistance (ASR) is 0.0027 Ω·cm2 at 800 °C. After 4 cooling cycle tests, the ASR increases to 0.0032 Ω·cm2 but lower than other samples. Meanwhile, the relative intense of Cr at the interface of SUS430 with MCO coatings fabricated by LPPS is lower than that of MCO fabricated by APS after 4 rising and cooling cycle operations, showing more favorable Cr diffusion inhibition performance.

关键词： interconnector coating     plasma spray     electrochemical performance     Cr diffusion inhibition     solid oxide cells (SOCs)    

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Experimental study of the effects of structured surface geometry on water spray cooling performance in

Minghou LIU, Yaqing WANG, Dong LIU, Kan XU, Yiliang CHEN

《能源前沿（英文）》 2011年 第5卷 第1期   页码 75-82 doi: 10.1007/s11708-010-0014-0

摘要： Experiments were conducted to study the effects of enhanced surfaces on heat transfer performance during water spray cooling in non-boiling regime. The surface enhancement is straight fin. The structures were machined on the top surface of heated copper blocks with a cross-sectional area of 10 mm×10 mm. The spray was performed using Unijet full cone nozzles with a volumetric flux of 0.044–0.053 m /(m ·s) and a nozzle height of 17 mm. It is found that the heat transfer is obviously enhanced for straight fin surfaces relative to the flat surface. However, the increment decreases as the fin height increases. For flat surface and enhanced surfaces with a fin height of 0.1 mm and 0.2 mm, as the coolant flux increases, the heat flux increases as well. However, for finned surface with a height of 0.4 mm, the heat flux is not sensitive to the coolant volumetric flux. Changed film thickness and the form of water/surface interaction due to an enhanced surface structure (different fin height) are the main reasons for changing of the local heat transfer coefficient.

关键词： spray cooling     finned surface     heat transfer    

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Removing ammonia from air with a constant pH, slightly acidic water　spray wet scrubber using recycled

Ahmad Kalbasi Ashtari, Amir M. Samani Majd, Gerald L. Riskowski, Saqib Mukhtar, Lingying Zhao

《环境科学与工程前沿（英文）》 2016年 第10卷 第6期 doi: 10.1007/s11783-016-0869-3

摘要： Slightly acidic solutions are a practical means of removing ammonia from air Scrubbed NH accumulates in solution as NH and should be an excellent fertilizer Increased air velocity decreased NH removal and increased NH collection Previous research on wet scrubbers has only studied highly acidic scrubbing solutions because of their high ammonia capture efficiencies; however, the high acidity created practical problems. Lower acidity solutions would reduce corrosion, maintenance, and cost; however, designers may need to use strategies for increasing scrubber effectiveness, such as using lower air velocities. The objective of this study was to determine if a spray scrubber with slightly acidic and higher pH scrubbing solution (pH from 2 to 8) could effectively remove NH from NH laden air (such as animal building exhaust air), and also collect this valuable resource for later use as a fertilizer. A bench-scale spray wet scrubber treated 20 ppmv NH /air mixture in a countercurrent contact chamber. First, the solution pH was varied from 2 to 8 while maintaining constant air velocity at 1.3 m·s . Next, air velocity was increased (2 and 3 m·s ) while solution pH remained constant at pH6. At 1.3 m·s , NH removal efficiencies ranged between 49.0% (pH8) and 84.3% (pH2). This study has shown that slightly acidic scrubbing solutions are a practical means of removing ammonia from air especially if the scrubber is designed to increase collisions between solution droplets and NH molecules. The NH removed from the air was held in solution as NH and accumulates over time so the solution should be an excellent fertilizer.

关键词： Ammonia     Spray wet scrubber     Slightly acidic scrubbing solution     Controlled pH     Removal efficiency    

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Impingement of hollow cone spray on hot porous medium

ZHAO Zhiguo, XIE Maozhao

《能源前沿（英文）》 2008年 第2卷 第3期   页码 273-278 doi: 10.1007/s11708-008-0048-8

摘要： To have a good understanding of the formation of homogenous mixture in a porous medium engine, the interaction between hollow cone spray and hot porous medium was studied numerically by using an improved version of KIVA-3V code. The improved KIVA-3V code is incorporated with an impingement model, heat transfer model and linearized instability sheet atomization (LISA) model to simulate the hollow cone spray. The reasonability of the impingement model and heat transfer model was validated. With a simple model to describe the structure of the porous medium, the interaction between hollow cone spray and hot porous medium was simulated under different ambient pressures and spray cone angles. Computational results show that the fuel spray could be divided into smaller ones, which provides conditions for the quick evaporation of fuel droplets and the mixing of fuel vapor with air. Differences in ambient pressure and spray cone angle affect the distribution of droplets in the porous medium.

关键词： improved version     simple     impingement     atomization     hollow    

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A study of spray granulation in vibrated fluidized bed with internal heating tubes

Xiaoheng PAN, Shichao YE, Zeguang ZHANG, Li ZHANG, Xuejun ZHU

《化学科学与工程前沿（英文）》 2009年 第3卷 第1期   页码 78-82 doi: 10.1007/s11705-009-0084-x

摘要： The granulation process in a vibrated fluidized bed with immersed horizontal heating tubes was studied in this paper, with small monoammonium phosphate particles as the initial particles and monoammonium phosphate solution sprayed on them. The concrete influences on the granulating performance of the immersed horizontal heating power, fluidizing gas velocity, vibration frequency and amplitude had been analyzed theoretically. The results show that appropriate vibration intensity is a preferred condition for the growth of partials, but the fine dust will become much more along with prolonged vibration. Increasing the heating power is beneficial to raise the growth rate. Particles will grow faster if the fluidizing gas velocity is higher, but this will cause more fine dust. The optimized condition of =0.002 m, =6.67 Hz, =1.4 m/s was given after the analysis of the experimental results. In the end, a semiempirical formula was derived from the experiment data, and the calculation results show good agreement with the experimental data.

关键词： vibrated fluidized bed     immersed horizontal     horizontal heating tubes     spray granulation     particle growth model    

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An experimental study on spray auto-ignition of RP-3 jet fuel and its surrogates

Yaozong DUAN, Wang LIU, Zhen HUANG, Dong HAN

《能源前沿（英文）》 2021年 第15卷 第2期   页码 396-404 doi: 10.1007/s11708-020-0715-y

摘要： Jet fuel is widely used in air transportation, and sometimes for special vehicles in ground transportation. In the latter case, fuel spray auto-ignition behavior is an important index for engine operation reliability. Surrogate fuel is usually used for fundamental combustion study due to the complex composition of practical fuels. As for jet fuels, two-component or three-component surrogate is usually selected to emulate practical fuels. The spray auto-ignition characteristics of RP-3 jet fuel and its three surrogates, the 70% mol -decane/30% mol 1,2,4-trimethylbenzene blend (Surrogate 1), the 51% mol -decane/49% mol 1, 2, 4-trimethylbenzene blend (Surrogate 2), and the 49.8% mol -dodecane/21.6% mol -cetane/28.6% mol toluene blend (Surrogate 3) were studied in a heated constant volume combustion chamber. Surrogate 1 and Surrogate 2 possess the same components, but their blending percentages are different, as the two surrogates were designed to capture the H/C ratio (Surrogate 1) and DCN (Surrogate 2) of RP-3 jet fuel, respectively. Surrogate 3 could emulate more physiochemical properties of RP-3 jet fuel, including molecular weight, H/C ratio and DCN. Experimental results indicate that Surrogate 1 overestimates the auto-ignition propensity of RP-3 jet fuel, whereas Surrogates 2 and 3 show quite similar auto-ignition propensity with RP-3 jet fuel. Therefore, to capture the spray auto-ignition behaviors, DCN is the most important parameter to match when designing the surrogate formulation. However, as the ambient temperature changes, the surrogates matching DCN may still show some differences from the RP-3 jet fuel, e.g., the first-stage heat release influenced by low-temperature chemistry.

关键词： RP-3 jet fuel     surrogate     spray auto-ignition     constant volume combustion chamber    

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Investigations on multicycle spray detonations

LI Mu, YAN Chuanjun, ZHENG Longxi, WANG Zhiwu, QIU Hua

《能源前沿（英文）》 2007年 第1卷 第2期   页码 207-212 doi: 10.1007/s00000-007-0027-5

摘要： Experimental investigations were carried out on a 50-I.D. multicycle pulse detonation engine (PDE) model, and liquid fuel (gasoline) was used. The average of pressure peak, as measured by piezoelectricity pressure transducer, increased versus distance to thrust wall before fully-developed detonation came into being. According to the pressure history, the pressure in detonation tube would not rise abruptly until the flame front advanced a certain distance downstream the spark. Just at that moment, two compression waves spreading to opposite direction were formed. One was enforced by combustion and became detonation rapidly. The other was weakened because of obstacles and insufficiency of fuel. Two methods were used to determine the induction length of two-phase detonation wave through the pressure history. Ignition delay time was found to be longer than deflagration-to-detonation transition (DDT) time, and the sum of the two would change little as cycle frequency increased. So they could be the most important factors controlling two-phase PDE frequency. Filling process and blowdown process were also analyzed.

关键词： multicycle     deflagration-to-detonation transition     pressure transducer     compression     piezoelectricity pressure    

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Spray characteristics of high-pressure swirl injector fueled with alcohol

WANG Xibin, CHEN Wansheng, GAO Jian, JIANG Deming, HUANG Zuohua

《能源前沿（英文）》 2007年 第1卷 第1期   页码 105-112 doi: 10.1007/s11708-007-0012-z

摘要： The spray characteristics of methanol and ethanol with high-pressure swirl injector were explored experimentally and numerically. Experimental results show that the spray characteristics of methanol and ethanol had displayed the same trends as that of gasoline. Under the low back-pressure ambient conditions, the spray behavior exhibited a hollow cone with wide spray angle and initial spray slug at the tip, while the spray presented a solid cone in the case of high back-pressure. Vortexes in the opposite direction existed in the rear part of the spray under low back-pressure ambient conditions while the vortexes formed in the middle part under high back-pressure ambient conditions. Experiments also showed that methanol had the largest cone angle, while ethanol and gasoline presented almost the same cone angle. Simulation results indicated that methanol and ethanol had a slightly larger Sauter mean diameter (SMD) than that of gasoline with swirl injector. The SMD profile of methanol coincided well with that of ethanol under low back-pressure ambient conditions, but displayed a slightly larger value under high back-pressure due to fuel evaporation. Numerical simulation could successfully demonstrate the spray characteristics of high-pressure swirl injector for methanol and ethanol fuels.

关键词： low back-pressure     diameter     initial spray     hollow     middle    

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核爆聚变电站──人类未来能源的希望

彭先觉,刘成安,陈银亮,郭 勤,尹文华,白云,陈小伟,屈明

《中国工程科学》 2008年 第10卷 第1期   页码 39-46

摘要：

详细介绍了核爆聚变电站的基本概念、组成、发展简史；提出了解决核爆炸实施安全、烧氘型核装置设计、核燃料生产回收等一系列问题的技术途径；对电站的技术可行性进行了分析论证，并比较了各种作为人类未来能源核能方案的前景。

关键词： 核爆聚变电站     爆洞     喷钠     烧氘型核装置     核燃料循环    

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Spray characteristics and controlling mechanism of fuel containing CO

Zhen HUANG, Jin XIAO, Xinqi QIAO, Gaozhi JIANG, Yiming SHAO, Seiichi SHIGA, Yasuhiro DAISHO

《能源前沿（英文）》 2012年 第6卷 第1期   页码 80-88 doi: 10.1007/s11708-012-0180-3

摘要： This paper presents studies of spray characteristics and controlling mechanism of fuel containing CO . Using diesel fuel containing CO gas, experiments were conducted on diesel hole-type nozzles and simple nozzles. The steady spray and transient spray characteristics were observed and measured by instantaneous shadowgraphy, high-speed photography, phase Doppler anemometry (PDA) and LDSA respectively. The effects of CO concentration in the fuel, the injection pressure, the nozzle ratio, surrounding gas pressure and temperature on the atomization behavior and spray pattern were evaluated. The results show that the injection of fuel containing CO can greatly improve the atomization and produce a parabolic-shaped spray; and the CO gas concentration, surrounding gas pressure, temperature and nozzle configuration have dominant influences on spray characteristics of the fuel containing CO . New insight into the controlling mechanism of atomization of the fuel containing CO was provided.

关键词： spray characteristics     fuel atomization     fuel containing CO2    

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A comparison of production system life cycle models

Rajesh ATTRI, Sandeep GROVER

《机械工程前沿（英文）》 2012年 第7卷 第3期   页码 305-311 doi: 10.1007/s11465-012-0332-5

摘要：

Companies today need to keep up with the rapidly changing market conditions to stay competitive. The main issues in this paper are related to a company’s market and its competitors. The prediction of market behavior is helpful for a manufacturing enterprise to build efficient production systems. However, these predictions are usually not reliable. A production system is required to adapt to changing markets, but such requirement entails higher cost. Hence, analyzing different life cycle models of the production system is necessary. In this paper, different life cycle models of the production system are compared to evaluate the distinctive features and the limitations of each model. Furthermore, the difference between product life cycle and production life cycle is summarized, and the effect of product life cycle on production life cycle is explained. Finally, a production system life cycle model, along with key activities to be performed in each stage, is proposed specifically for the manufacturing sector.

关键词： production system     life cycle     model     product    

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标题 作者 时间 类型 操作

Kinetic studies of xylan hydrolysis of corn stover in a dilute acid cycle spray flow-through reactor

Hongman ZHANG, Qiang JIN, Rui XU, Lishi YAN, Zengxiang LIN

期刊论文

燃油喷雾形态主动控制的可能性

Masataka Arai

期刊论文

Numerical investigation of the effects of fuel spray type on the interaction of fuel spray and hot porous

ZHAO Zhiguo, XIE Maozhao

期刊论文

Particle formation of hydroxyapatite precursor containing two components in a spray pyrolysis process

W. Widiyastuti, Adhi Setiawan, Sugeng Winardi, Tantular Nurtono, Heru Setyawan

期刊论文

Plasma spray coating on interconnector toward promoted solid oxide fuel cells and solid oxide electrolysis

期刊论文

Experimental study of the effects of structured surface geometry on water spray cooling performance in

Minghou LIU, Yaqing WANG, Dong LIU, Kan XU, Yiliang CHEN

期刊论文

Removing ammonia from air with a constant pH, slightly acidic water　spray wet scrubber using recycled

Ahmad Kalbasi Ashtari, Amir M. Samani Majd, Gerald L. Riskowski, Saqib Mukhtar, Lingying Zhao

期刊论文

Impingement of hollow cone spray on hot porous medium

ZHAO Zhiguo, XIE Maozhao

期刊论文

A study of spray granulation in vibrated fluidized bed with internal heating tubes

Xiaoheng PAN, Shichao YE, Zeguang ZHANG, Li ZHANG, Xuejun ZHU

期刊论文

An experimental study on spray auto-ignition of RP-3 jet fuel and its surrogates

Yaozong DUAN, Wang LIU, Zhen HUANG, Dong HAN

期刊论文

Investigations on multicycle spray detonations

LI Mu, YAN Chuanjun, ZHENG Longxi, WANG Zhiwu, QIU Hua

期刊论文

Spray characteristics of high-pressure swirl injector fueled with alcohol

WANG Xibin, CHEN Wansheng, GAO Jian, JIANG Deming, HUANG Zuohua

期刊论文

核爆聚变电站──人类未来能源的希望

彭先觉,刘成安,陈银亮,郭 勤,尹文华,白云,陈小伟,屈明

期刊论文

Spray characteristics and controlling mechanism of fuel containing CO

Zhen HUANG, Jin XIAO, Xinqi QIAO, Gaozhi JIANG, Yiming SHAO, Seiichi SHIGA, Yasuhiro DAISHO

期刊论文

A comparison of production system life cycle models

Rajesh ATTRI, Sandeep GROVER

期刊论文